CobaltMaghrebV1, Main, Exploration, bibRecord, 000A54

Structural and ionic transport studies of LiAlyCo1+yO2 nano-structured intercalation compounds

Identifieur interne : 000A54 ( Main/Exploration ); précédent : 000A53; suivant : 000A55

Structural and ionic transport studies of LiAlyCo1+yO2 nano-structured intercalation compounds

Auteurs : N. Amdouni [France, Tunisie] ; H. Zarrouk [Tunisie] ; F. Soulette [France] ; C. Julien [France]

Source :

Proceedings - Electrochemical society [ 0161-6374 ] ; 2003.

RBID : Pascal:05-0330155

Descripteurs français

Pascal (Inist)
- Batterie électrique, Lithium ion, Composé insertion, Propriété électrochimique, Cathode, Matériau électrode, Lithium oxyde, Aluminium oxyde, Cobalt oxyde.

English descriptors

KwdEn :
- Aluminium oxide, Cathode, Cobalt oxide, Electric batteries, Electrochemical properties, Electrode material, Intercalation compound, Lithium ion, Lithium oxide.

Abstract

We present the electrochemical features behavior of LiAl_yCo_1-yO₂ (0.0≤y≤0.3) electrodes prepared by "chimie douce" using the citrate route. The phase evolution was studied as a function of the aluminum substitution and the modification on the intercalation and deintercalation of Li ions. The overall electrochemical capacity of the LiAl_yCo_1-yO₂ oxides have been reduced due to the sp metal substitution, however, a more stable charge-discharge cycling performances have been observed when electrodes are charged up to 4.3 V as compared to the performance of the native oxide. For such a cut-off voltage, the charge capacity of the Li//LiAl_0.2Co_0.8O₂ cell is ca. 118 mAh/g. Kinetics characterized by the GITT method show enhancement of the chemical diffusion coefficients upon Al substitution in the LiAl_yCo_1-yO₂ matrix.

Affiliations:

Links toward previous steps (curation, corpus...)

to stream PascalFrancis, to step Corpus: 000185
to stream PascalFrancis, to step Curation: 000110
to stream PascalFrancis, to step Checkpoint: 000219
to stream Main, to step Merge: 000A68
to stream Main, to step Curation: 000A54

Le document en format XML

<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en" level="a">Structural and ionic transport studies of LiAl<sub>y</sub>
Co<sub>1+y</sub>
O<sub>2</sub>
 nano-structured intercalation compounds</title>
<author><name sortKey="Amdouni, N" sort="Amdouni, N" uniqKey="Amdouni N" first="N." last="Amdouni">N. Amdouni</name>
<affiliation wicri:level="4"><inist:fA14 i1="01"><s1>LMDH, CNRS-UMR 7603, Université Pierre et Marie Curie, 4 place Jussieu, case 86</s1>
<s2>75252 Paris</s2>
<s3>FRA</s3>
<sZ>1 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>4 aut.</sZ>
</inist:fA14>
<country>France</country>
<placeName><region type="region" nuts="2">Île-de-France</region>
<settlement type="city">Paris</settlement>
</placeName>
<orgName type="university">Université Pierre-et-Marie-Curie</orgName>
</affiliation>
<affiliation wicri:level="4"><inist:fA14 i1="02"><s1>LCM, Université de Tunis El Manar, Campus Universitaire</s1>
<s2>2092 El Manar II</s2>
<s3>TUN</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
</inist:fA14>
<country>Tunisie</country>
<wicri:noRegion>2092 El Manar II</wicri:noRegion>
<orgName type="university">Université de Tunis - El Manar</orgName>
<placeName><settlement type="city">Tunis</settlement>
<region type="region" nuts="2">Gouvernorat de Tunis</region>
</placeName>
</affiliation>
</author>
<author><name sortKey="Zarrouk, H" sort="Zarrouk, H" uniqKey="Zarrouk H" first="H." last="Zarrouk">H. Zarrouk</name>
<affiliation wicri:level="4"><inist:fA14 i1="02"><s1>LCM, Université de Tunis El Manar, Campus Universitaire</s1>
<s2>2092 El Manar II</s2>
<s3>TUN</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
</inist:fA14>
<country>Tunisie</country>
<wicri:noRegion>2092 El Manar II</wicri:noRegion>
<orgName type="university">Université de Tunis - El Manar</orgName>
<placeName><settlement type="city">Tunis</settlement>
<region type="region" nuts="2">Gouvernorat de Tunis</region>
</placeName>
</affiliation>
</author>
<author><name sortKey="Soulette, F" sort="Soulette, F" uniqKey="Soulette F" first="F." last="Soulette">F. Soulette</name>
<affiliation wicri:level="4"><inist:fA14 i1="01"><s1>LMDH, CNRS-UMR 7603, Université Pierre et Marie Curie, 4 place Jussieu, case 86</s1>
<s2>75252 Paris</s2>
<s3>FRA</s3>
<sZ>1 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>4 aut.</sZ>
</inist:fA14>
<country>France</country>
<placeName><region type="region" nuts="2">Île-de-France</region>
<settlement type="city">Paris</settlement>
</placeName>
<orgName type="university">Université Pierre-et-Marie-Curie</orgName>
</affiliation>
</author>
<author><name sortKey="Julien, C" sort="Julien, C" uniqKey="Julien C" first="C." last="Julien">C. Julien</name>
<affiliation wicri:level="4"><inist:fA14 i1="01"><s1>LMDH, CNRS-UMR 7603, Université Pierre et Marie Curie, 4 place Jussieu, case 86</s1>
<s2>75252 Paris</s2>
<s3>FRA</s3>
<sZ>1 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>4 aut.</sZ>
</inist:fA14>
<country>France</country>
<placeName><region type="region" nuts="2">Île-de-France</region>
<settlement type="city">Paris</settlement>
</placeName>
<orgName type="university">Université Pierre-et-Marie-Curie</orgName>
</affiliation>
</author>
</titleStmt>
<publicationStmt><idno type="wicri:source">INIST</idno>
<idno type="inist">05-0330155</idno>
<date when="2003">2003</date>
<idno type="stanalyst">PASCAL 05-0330155 INIST</idno>
<idno type="RBID">Pascal:05-0330155</idno>
<idno type="wicri:Area/PascalFrancis/Corpus">000185</idno>
<idno type="wicri:Area/PascalFrancis/Curation">000110</idno>
<idno type="wicri:Area/PascalFrancis/Checkpoint">000219</idno>
<idno type="wicri:explorRef" wicri:stream="PascalFrancis" wicri:step="Checkpoint">000219</idno>
<idno type="wicri:doubleKey">0161-6374:2003:Amdouni N:structural:and:ionic</idno>
<idno type="wicri:Area/Main/Merge">000A68</idno>
<idno type="wicri:Area/Main/Curation">000A54</idno>
<idno type="wicri:Area/Main/Exploration">000A54</idno>
</publicationStmt>
<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a">Structural and ionic transport studies of LiAl<sub>y</sub>
Co<sub>1+y</sub>
O<sub>2</sub>
 nano-structured intercalation compounds</title>
<author><name sortKey="Amdouni, N" sort="Amdouni, N" uniqKey="Amdouni N" first="N." last="Amdouni">N. Amdouni</name>
<affiliation wicri:level="4"><inist:fA14 i1="01"><s1>LMDH, CNRS-UMR 7603, Université Pierre et Marie Curie, 4 place Jussieu, case 86</s1>
<s2>75252 Paris</s2>
<s3>FRA</s3>
<sZ>1 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>4 aut.</sZ>
</inist:fA14>
<country>France</country>
<placeName><region type="region" nuts="2">Île-de-France</region>
<settlement type="city">Paris</settlement>
</placeName>
<orgName type="university">Université Pierre-et-Marie-Curie</orgName>
</affiliation>
<affiliation wicri:level="4"><inist:fA14 i1="02"><s1>LCM, Université de Tunis El Manar, Campus Universitaire</s1>
<s2>2092 El Manar II</s2>
<s3>TUN</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
</inist:fA14>
<country>Tunisie</country>
<wicri:noRegion>2092 El Manar II</wicri:noRegion>
<orgName type="university">Université de Tunis - El Manar</orgName>
<placeName><settlement type="city">Tunis</settlement>
<region type="region" nuts="2">Gouvernorat de Tunis</region>
</placeName>
</affiliation>
</author>
<author><name sortKey="Zarrouk, H" sort="Zarrouk, H" uniqKey="Zarrouk H" first="H." last="Zarrouk">H. Zarrouk</name>
<affiliation wicri:level="4"><inist:fA14 i1="02"><s1>LCM, Université de Tunis El Manar, Campus Universitaire</s1>
<s2>2092 El Manar II</s2>
<s3>TUN</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
</inist:fA14>
<country>Tunisie</country>
<wicri:noRegion>2092 El Manar II</wicri:noRegion>
<orgName type="university">Université de Tunis - El Manar</orgName>
<placeName><settlement type="city">Tunis</settlement>
<region type="region" nuts="2">Gouvernorat de Tunis</region>
</placeName>
</affiliation>
</author>
<author><name sortKey="Soulette, F" sort="Soulette, F" uniqKey="Soulette F" first="F." last="Soulette">F. Soulette</name>
<affiliation wicri:level="4"><inist:fA14 i1="01"><s1>LMDH, CNRS-UMR 7603, Université Pierre et Marie Curie, 4 place Jussieu, case 86</s1>
<s2>75252 Paris</s2>
<s3>FRA</s3>
<sZ>1 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>4 aut.</sZ>
</inist:fA14>
<country>France</country>
<placeName><region type="region" nuts="2">Île-de-France</region>
<settlement type="city">Paris</settlement>
</placeName>
<orgName type="university">Université Pierre-et-Marie-Curie</orgName>
</affiliation>
</author>
<author><name sortKey="Julien, C" sort="Julien, C" uniqKey="Julien C" first="C." last="Julien">C. Julien</name>
<affiliation wicri:level="4"><inist:fA14 i1="01"><s1>LMDH, CNRS-UMR 7603, Université Pierre et Marie Curie, 4 place Jussieu, case 86</s1>
<s2>75252 Paris</s2>
<s3>FRA</s3>
<sZ>1 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>4 aut.</sZ>
</inist:fA14>
<country>France</country>
<placeName><region type="region" nuts="2">Île-de-France</region>
<settlement type="city">Paris</settlement>
</placeName>
<orgName type="university">Université Pierre-et-Marie-Curie</orgName>
</affiliation>
</author>
</analytic>
<series><title level="j" type="main">Proceedings - Electrochemical society</title>
<idno type="ISSN">0161-6374</idno>
<imprint><date when="2003">2003</date>
</imprint>
</series>
</biblStruct>
</sourceDesc>
<seriesStmt><title level="j" type="main">Proceedings - Electrochemical society</title>
<idno type="ISSN">0161-6374</idno>
</seriesStmt>
</fileDesc>
<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Aluminium oxide</term>
<term>Cathode</term>
<term>Cobalt oxide</term>
<term>Electric batteries</term>
<term>Electrochemical properties</term>
<term>Electrode material</term>
<term>Intercalation compound</term>
<term>Lithium ion</term>
<term>Lithium oxide</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Batterie électrique</term>
<term>Lithium ion</term>
<term>Composé insertion</term>
<term>Propriété électrochimique</term>
<term>Cathode</term>
<term>Matériau électrode</term>
<term>Lithium oxyde</term>
<term>Aluminium oxyde</term>
<term>Cobalt oxyde</term>
</keywords>
</textClass>
</profileDesc>
</teiHeader>
<front><div type="abstract" xml:lang="en">We present the electrochemical features behavior of LiAl<sub>y</sub>
Co<sub>1-y</sub>
O<sub>2</sub>
 (0.0≤y≤0.3) electrodes prepared by "chimie douce" using the citrate route. The phase evolution was studied as a function of the aluminum substitution and the modification on the intercalation and deintercalation of Li ions. The overall electrochemical capacity of the LiAl<sub>y</sub>
Co<sub>1-y</sub>
O<sub>2</sub>
 oxides have been reduced due to the sp metal substitution, however, a more stable charge-discharge cycling performances have been observed when electrodes are charged up to 4.3 V as compared to the performance of the native oxide. For such a cut-off voltage, the charge capacity of the Li//LiAl<sub>0.2</sub>
Co<sub>0.8</sub>
O<sub>2</sub>
 cell is ca. 118 mAh/g. Kinetics characterized by the GITT method show enhancement of the chemical diffusion coefficients upon Al substitution in the LiAl<sub>y</sub>
Co<sub>1-y</sub>
O<sub>2</sub>
 matrix.</div>
</front>
</TEI>
<affiliations><list><country><li>France</li>
<li>Tunisie</li>
</country>
<region><li>Gouvernorat de Tunis</li>
<li>Île-de-France</li>
</region>
<settlement><li>Paris</li>
<li>Tunis</li>
</settlement>
<orgName><li>Université Pierre-et-Marie-Curie</li>
<li>Université de Tunis - El Manar</li>
</orgName>
</list>
<tree><country name="France"><region name="Île-de-France"><name sortKey="Amdouni, N" sort="Amdouni, N" uniqKey="Amdouni N" first="N." last="Amdouni">N. Amdouni</name>
</region>
<name sortKey="Julien, C" sort="Julien, C" uniqKey="Julien C" first="C." last="Julien">C. Julien</name>
<name sortKey="Soulette, F" sort="Soulette, F" uniqKey="Soulette F" first="F." last="Soulette">F. Soulette</name>
</country>
<country name="Tunisie"><region name="Gouvernorat de Tunis"><name sortKey="Amdouni, N" sort="Amdouni, N" uniqKey="Amdouni N" first="N." last="Amdouni">N. Amdouni</name>
</region>
<name sortKey="Zarrouk, H" sort="Zarrouk, H" uniqKey="Zarrouk H" first="H." last="Zarrouk">H. Zarrouk</name>
</country>
</tree>
</affiliations>
</record>

Pour manipuler ce document sous Unix (Dilib)

EXPLOR_STEP=$WICRI_ROOT/Wicri/Terre/explor/CobaltMaghrebV1/Data/Main/Exploration

HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 000A54 | SxmlIndent | more

HfdSelect -h $EXPLOR_AREA/Data/Main/Exploration/biblio.hfd -nk 000A54 | SxmlIndent | more

Pour mettre un lien sur cette page dans le réseau Wicri

{{Explor lien
   |wiki=    Wicri/Terre
   |area=    CobaltMaghrebV1
   |flux=    Main
   |étape=   Exploration
   |type=    RBID
   |clé=     Pascal:05-0330155
   |texte=   Structural and ionic transport studies of LiAlyCo1+yO2 nano-structured intercalation compounds
}}

This area was generated with Dilib version V0.6.32.
Data generation: Tue Nov 14 12:56:51 2017. Site generation: Mon Feb 12 07:59:49 2024

	Serveur d'exploration sur le cobalt au Maghreb
	Attention, ce site est en cours de développement ! Attention, site généré par des moyens informatiques à partir de corpus bruts. Les informations ne sont donc pas validées.

Serveur d'exploration sur le cobalt au Maghreb

Structural and ionic transport studies of LiAlyCo1+yO2 nano-structured intercalation compounds

Structural and ionic transport studies of LiAlyCo1+yO2 nano-structured intercalation compounds

Source :

Descripteurs français

English descriptors

Abstract

Links toward previous steps (curation, corpus...)

Le document en format XML

Pour manipuler ce document sous Unix (Dilib)

Pour mettre un lien sur cette page dans le réseau Wicri